Synthetic line has two additional considerations when spooling. The reduction in drum friction (over steel cable), which means that a minimum of eight wraps must be on the drum to pull a load, sometime 10, depending on the rope attachment method and drum finish (steel cable is typically 5 wraps). And because of the "slippery" nature of dyneema, the synthetic line will constrict under load, both around the drum (which can crush some drums, like consumer Warn winches above 9,500lbs.), but also constrict and heat-up, smear and otherwise damage the synthetic cable if not spooled properly.
As mentioned above, this should be done under a load, usually another vehicle as the connection point with the a driver present and applying moderate brake pressure (the parking brake can also be used). All winching safety rules apply while tensioning and spooling. Tension will be obvious, as the "tone" of the winch motor and gearing will change and a visible tensioning of the line will occur. Obviously, without having a strain guage, there is no precise way to do this, so the goal is a moderate and controlled load.
This process is critical to your line having a long service life, and should be repeated after each use. Take that opportunity to also inspect the line for any damage and clean it. Fortunately, synthetic line is quite easy to clean in a bucket of warm water and woolite. You can easily open up the strands of the rope (like Amsteel Blue) with a simple technique (but hard to describe) of using both hands and holding the rope with a 4-5" gap between each hand and then pushing the hands together, sliding another 4-5" and repeating. I will try to post some pictures of this.
Unfortunately, it is common for some to recommend stepping on the line (of course, never step
over a loaded line). Since we are not in the Outback Challenge, we should not be in a rush anyways, and can plan our rigging to eliminate most requirements of stepping on the line, and those we cannot, just walk around the vehicle or anchor. Stepping on the line drives dirt and other matter into the strands, cutting the fibers and shortening the life.
This will provide some help:
Viking OffRoad Line Installation Instructions